The five-time champion beat British hopeful Johanna Konta in the semi-final, and will face the Spaniard who is looking to win the Venus Rosewater Dish for the first time.
Williams is the oldest Grand Slam finalist since Martina Navratilova was runner-up at Wimbledon 23 years ago, a few months before Muguruza was born.
The pair are first up on Centre Court, ahead of the men’s doubles final and, third in line, the ladies’ doubles final.
- Read more
Wimbledon ladies’ final: Venus Williams vs Garbine Muguruza
Lukasz Kubot and Marcelo Melo, no.4 seeds from Poland and Brazil respectively, face Austria’s Oliver Marach and Croatia’s Mate Pavic, no.16 seeds, after the ladies’ final.
Then it’s back to the ladies as Hao-Ching Chan and Monica Niculescu, the no.9 seeds, try to upset no.2 seeds Ekaterina Makarova and Elena Vesina from Russia.
Scroll down for the Order of Play so far…